The Ozone Layer and the Montreal Protocol

Freon kills ozone

  • 1930: Thomas Midgley invents freon
    • HCFC&CFC, produced by DuPont de Nemours
    • Neutral gaz, no corrosion, not active, not toxic, highly efficient to carry heat (compression/decompression cycles)
    • Largely used for refrigeration (fridges, air cooler), solvent, fire extinguisher, spray propelant, plastic foam propulsion


  • But: interact with O3 and UV, and destroy it in the upper layer of atmosphere
    • O3 layer blocks 97-99% of UV radiation
    • mostly UV-a and b lethal radiation, Dobson discovered this in the 30-50’s


  • 1985: measure of the ozone layer display a large hole (over Antarctic)
    • Farman, Nature ; Rowland&Molina had found the mecanism in 1974 (and a Nobel prize)
    • 25y. of O3 hole could have caused 1 to 2 millions skin cancers
    • Around 200 000 victims in the US up to 2040, according to NASA

Montreal Protocol

  • 1985: Vienna convention (20 countries)
    • 1985-1987: strong action from CFC lobbies
    • DuPont, 1987 “we believe that there is no immediate crisis that demands unilateral regulation”
  • 1987: Montreal protocol
    • ban use of CFC (immediate) and HCFC (to come) in most of the applications
    • 196 states, including USA
    • Revised 7 times, last revision being Bejing in 1999
  • Phasing out of CFC production and consumption by 1996,
    • HCFC levels freezed by 2013 (transitory substitution), starting reduction by 2015
    • Multilateral fund for the Implementation of the Montreal Protocol
    • US$ 2.1 billions for countries with less than 0.3kg/cap/year ODS consumption
    • 147/196 are potential receivers from the fund
  • It worked!
  • It is expected than ozone hole will disapear in 2045-2050
    • wouldn’t it, we’ll be all dead (or nearly)

Climate change vs Ozone layer

(Why) it’s complicated

Your plan, your priorities